Clebsch-Gordan coefficients are mathematical symbol used to integrate products of three spherical harmonics. Clebsch-Gordan coefficients commonly arise in applications involving the addition of angular momentum in quantum mechanics. If products of more than three spherical harmonics are desired, then a generalization known as Wigner 6j-symbols or Wigner 9j-symbols is used.
The Clebsch-Gordan coefficients are variously written as , , , or . The Clebsch-Gordan coefficients are implemented in the Wolfram Language as ClebschGordan[j1, m1, j2, m2, j, m].
The Clebsch-Gordan coefficients are defined by
(1)
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where , and satisfy
(2)
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for .
Care is needed in interpreting analytic representations of Clebsch-Gordan coefficients since these coefficients are defined only on measure zero sets. As a result, "generic" symbolic formulas may not hold it certain cases, if at all. For example, ClebschGordan[1, 0, j2, 0, 2, 0] evaluates to an expression that is "generically" correct but not correct for the special case , whereas ClebschGordan[1, 0, 1, 0, 2, 0] evaluates to the correct value .
The coefficients are subject to the restrictions that be positive integers or half-integers, is an integer, are positive or negative integers or half integers,
(3)
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(4)
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(5)
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and , , and (Abramowitz and Stegun 1972, p. 1006). In addition, by use of symmetry relations, coefficients may always be put in the standard form and .
The Clebsch-Gordan coefficients are sometimes expressed using the related Racah V-coefficients,
(6)
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or Wigner 3j-symbols. Connections among the three are
(7)
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(8)
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(9)
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They have the symmetry
(10)
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and obey the orthogonality relationships
(11)
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(12)
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